I never did with pwc, but I assume they're pretty much the same. I did with DT, behavioral of course.
The following discussion board has many good info. for big4 interview. Most people there are big4ers or interns.
http://www.accounting.com/forum2/forum_posts.asp?TID=5213&KW=interview
http://www.accounting.com/forum2/forum_posts.asp?TID=3912&KW=interview
Really no need to worry, believe me (although I know you don't :p). As long as you behave professionally, don't make big mistakes (like I did once), you'll be okay. Good luck!